Pdf we have reported herein the synthesis of three new cuii complexes of tri and tetradentate schiff base ligands containing n3 or n4 donor. The coordination of neutral monodentate schiff bases. On the basis of the spectral studies show that the schiff bases act as monodentate and an octahedral geometry has been assigned for feii and niii complexes. The schiff s base act as a bidentate monobasic donor for cuii, coii, niii, mnii and feii and prominent sites of coordination are nitrogen of azomethine group and oxygen of the hydroxyl group. The schiff bases and the new complexes were tested in vitro to evaluate their activity against the fungus aspergillus flavus. The electrochemical and photoluminescence properties of the schiff bases were investigated in the different conditions. Copper, cobalt and zincii complexes with monofunctional bidentate schiff base and monodentate neutral ligands.
Synthesis and characterization of some transition metal complexes derived from bidentate schiff base. Carbonyl metal derivatives of schiff bases and schiff base. An unprecedented monodentate bonding mode of the potentially tridentate ligand. Srividhya2 chemistry, the madura college, madurai kamaraj university, india chemistry, psna college of engineering and technology anna university, india abstract. Keywords physical chemistry inorganic chemistry pyridine aspergillus aniline. Pdf new cuii complexes with polydentate chelating schiff base. Synthesis of metal complexes fe ii, co ii, ni ii of monodentate. Pdf applications of vanillin schiff base ligands and their.
Following are some of the examples which show the complexing nature of schiff s bases. Novel metalii complexes with bidentate schiff base ligand. The new schiff bases are synthesis from various and aldehyde and amine under magnetic stirrer. Their structural characterization, photoluminescence, anticancer, electrochemical and sensor properties. Rutheniumii complexes containing bidentate schiff bases. Schiff bases derived from salicylaldehyde and vari. The schiff bases can be formed by the condensation of a primary amine with a carbonyl compound and they con tain an azomethine group chn.
Polydentate schiffbase ligands and their cdii and cuii metal. A novel copperii complex with a pendant schiff base. Synthesis, characterization, microbiological activity and electrochemical properties of the schiffbase ligands a1a5 and their cdii and cuii metal complexes. The resultant compound, r 1 r 2 cnr 3 is called a schiff base, where r 1 is an aryl group, r 2 is a hydrogen atom and r 3 is either an alkyl or aryl group. Bydirect interaction of the schiff base with the metal salts the schiff base can be synthesized without using the metal ion and then followed by addition of the metal ion as salt solution for complex formation. Synthesis and characterization of some transition metal. Monodentate, didentate, and tridentate ligation of a schiffbase ligand in a tetranuclear zincii complex article in bulletin of the chemical society of japan 741. These schiff bases can act as a ligand due to the lone pair of electrons on nitrogen atom of the azomethine group. Pdf copper, cobalt and zincii complexes with monofunctional. Pdf a novel copperii complex with a pendant schiff. This can be easily described by the following example.